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No deceased, only living couples please.

The obvious ones that come to mind:

Brad Pitt and Angelina Jolie
Tom Cruise and Nicole Kidman
Ethan Hawke and Uma Thurman
Will Smith and Jada Pinkett Smith
Humphrey Bogart and Lauren Bacall
Bruce Willis and Demi Moore

Ryan Phillipe and Reese Witherspoon

Nina Dobrev and Ian Somerhalder

Ethan Hawke and Uma Thurman

Will Smith and Jada Pinkett-Smith

Lisa Bonet and Jason Momoa

Easy one there:

Christopher and Lynda Day George

Got to go with Newman and Woodward.

Antonio Benderas and Melanie Griffith
Warren Beatty and Annette Bening
Ed Harris and Amy Madigan
Paul Newman and Joan Woodward (R.I.P)

Emma Thompson and Kenneth Branaugh
Sean Penn and Robin Wright
Vivian Leigh and Laurence Olivier
Joan Plowright and Laurence Olivier
Sian Phillips and Peter O’Toole
Monica Belluci and Vincent Cassel