there is leeway into what exactly is meant by "peak human."
superhero stories were birthed in a time when our understanding of science was still blooming. thus, much, if not all, of superhero lore is steeped in pseudoscience. we sincerely believed that science would solve all of our problems--this optimism was actually shown on-screen in the MCU. we sincerely thought that radiation might grant super powers. we sincerely thought we would have flying cars by the year 2000, that we would have colonized distant worlds, etc., etc. then we realized that science is a lot of hard work.
the captain america origin story was similarly birthed in a time when our understanding of evolution was skewed. we believed (and still do) that it is somewhat all about us (it isn't), and that human beings have not reached some anthropomorphized version of "peak." we assume "peak" to mean faster, stronger, smarter, etc.., etc. unfortunately, evolution is NOT about us, and doesn't care about what we perceive as stronger, faster, or smarter. it only cares about what is more adaptable--if that means small and squishy, that's what will survive (think cockroaches). thus, captain america lore has his "peak human strength" as being able to lift something like 1000 lb. back when cap was conceived, it was possible to dream something like this was possible, but we're just not built to handle that kind of weight (even powerlifters require support). thus, realistically, whatever the serum made cap, it is significantly more than human. but this is also why realism will never ever be the right metric by which to measure comic books.
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