The aliens would not have used Pi. It's a human convention.
The only reason we use Pi = 3.1415926 is because the first person to calculate it did so using the diameter of the circle. It's defined as Circumference/diameter. In other words, it's how many times the diameter of the circle fits into the circumference of the circle. But the earlier humans who discovered this didn't realize that the diameter is not the fundamental measurement of the circle. It's just easier to measure...hence we get stuck with a convention of Pi = 3.14. And since we do all our math with the radius (the truly fundamental measurement of a circle), Pi only represents half the circle in radians. If we used a unit of diametans, then Pi would actually make some sense.
Surely an advanced, intelligent race of aliens would have defined Pi (or "blork" as they would surely call it) as 6.2831...
Ever notice how 2*Pi shows up in all the math equations? Because you have to have 2 of them to get all the way around the circle. Ever notice how 1/4 of the circle is 1/2 Pi? However, if Pi had been defined as 6.2831 (as Euler occasionally used), 1/4 of the circle would be 1/4 Pi. It's a better convention. History is full of these kinds of "mistakes". We just recognize them, and move on.
I find it hard to believe aliens would be using Pi, unless they were intentionally telling us something about half a circle, instead of a full circle.
A lot of people are recognizing the problem now, but there seems to be too much cultural momentum to fix it.
If this topic interests you, please read these articles.
"Pi is Wrong!" - Bob Palais
http://www.math.utah.edu/~palais/pi.pdf
"What really worries me is that the first thing we broadcast to the cosmos to demonstrate our 'intelligence' is 3.14. I am a bit concerned about what the lifeforms who receive it will do after they stop laughing at the creatures who must rarely question orthodoxy."
http://www.tauday.com
Lots of proofs why Pi is not the right circle constant.