When Gerard shot Kimble in the head...
Remember that scene where Kimble got his foot stuck in the bulletproof door, and he tried to pull it out, so Gerard shot him a few times in the chest. Kimble fell down, and then Gerard executed him with a bullet to the head once he was on the ground. Remember, at this point Gerard didn't know the glass was bulletproof. It looked like Kimble fell down because he was wounded from the bullets in his chest. So basically, Gerard decided to execute an unarmed wounded man just lying on the ground. I'm not complaining, I find it funny.
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