Just to be clear, by brownface, do you mean a white actor playing a hispanic/mexican character? Just asking, cause I get irked when a white actor plays an Indian.
anyway, Pedro Armendáriz is a well regarded mexican actor and you'll find him in several popular westerns including 3 Godfathers & The Wonderful Country. My personal favorite is Fort Apache, he has a co-starring role in it but it's a very important one.
Anthony Quinn is another very popular actor with a laundry list of very popular western titles in his resume. Some of my favorites are Warlock, Last Train from Gun Hill, The Ox-bow Incident & Ride Vaquero!.
Diego Luna has a significant co-starring role in Open Range.
Fernando Lamas, father of Lornezo Lamas, stars in 100 Rifles.
Katy Jurado has prominent roles in lots of westerns including High Noon & Broken Lance and many others.
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